Stereospecific S(N)2@P reactions: novel access to bulky P-stereogenic ligands.
نویسندگان
چکیده
The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 99 شماره
صفحات -
تاریخ انتشار 2015